Bu4N+ alkoxide-initiated/autocatalytic addition reactions with organotrimethylsilanes.
نویسندگان
چکیده
The use of Me3SiO(-)/Bu4N(+) as a general activator of organotrimethylsilanes for addition reactions has been established. The broad scope of the method offers trimethylsilanes (including acetate, allyl, propargyl, benzyl, dithiane, heteroaryl, and aryl derivatives) as bench-stable organometallics that can be readily utilized as carbanion equivalents for synthesis. Reactions are achieved at rt without the requirement of specialized precautions that are commonplace for other organometallics.
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ورودعنوان ژورنال:
- The Journal of organic chemistry
دوره 79 12 شماره
صفحات -
تاریخ انتشار 2014